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Abstract:
Niobium nitride (δ-NbN) coatings were deposited on AISI 316L austenitic steel using reactive DC magnetron sputtering. This study investigates the effects of air oxidation on the surface morphology, topography, roughness, nanohardness, adhesion, and wear resistance of NbN coatings. Their microstructure and thickness were analyzed by scanning electron microscopy (SEM), while surface morphology and roughness were assessed using atomic force microscopy (AFM), and surface topography was assessed by an optical profilometer. Nanohardness was measured using a Berkovich indenter. Adhesion was evaluated via progressive-load scratch testing and Rockwell indentation (VDI 3198 standard). Wear resistance was assessed using the “ball-on-disk” method. Both as-deposited and oxidized NbN coatings improved the mechanical performance of the substrate surface. Air oxidation led to the formation of an orthorhombic Nb2O5 surface layer, which increased surface roughness and reduced hardness. However, the brittle oxide also contributed to a lower coefficient of friction. Despite reduced adhesion and increased surface development, the oxidized coating exhibited a significantly lower wear rate than the uncoated steel, though several times higher than that of the non-oxidized NbN. Considering its good wear and corrosion performance, along with the bioactivity confirmed in earlier research, the oxidized NbN coating can be considered a promising candidate for biomedical applications.

Keywords:
Nb2O5, NbN, magnetron sputtering, oxidation, adhesion, wear, surface engineering