Institute of Fundamental Technological Research
Polish Academy of Sciences

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Lijang Guo

South China Normal Universit (CN)

Recent publications
1.  Yang H., Akinoglu E.M., Guo L., Jin M., Zhou G., Giersig M., Shui L., Mulvaney P., A PTFE helical capillary microreactor for the high throughput synthesis of monodisperse silica particles, Chemical Engineering Journal, ISSN: 1385-8947, DOI: 10.1016/j.cej.2020.126063, Vol.401, pp.126063-1-29, 2020

Abstract:
We propose a simple and inexpensive SiO2 submicron particle synthesis method based on a PTFE helical capillary microreactor. The device is based on Dean flow mediated, ultrafast mixing of two liquid phases in a microfluidic spiral pipe. Excellent control of particle size between 100 nm and 600 nm and narrow polydispersity can be achieved by controlling the device and process parameters. Numerical simulations are performed to determine the optimal device dimensions. In the mother liquor the silica particles exhibit zeta potentials < -60 mV, rendering them very stable even at high particle volume fractions. The current device typically produces around 0.234 g/h of the silica particles.

Keywords:
SiO2 particle synthesis, continuous flow synthesis, helical capillary microreactor

Affiliations:
Yang H. - South China Normal Universit (CN)
Akinoglu E.M. - University of Melbourne (AU)
Guo L. - South China Normal Universit (CN)
Jin M. - South China Normal Universit (CN)
Zhou G. - South China Normal Universit (CN)
Giersig M. - IPPT PAN
Shui L. - South China Normal Universit (CN)
Mulvaney P. - University of Melbourne (AU)
2.  Akinoglu E.M., Luo L., Dodge T., Guo L., Akinoglu G.E., Wang X., Shui L., Zhou G., Naughton M.J., Kempa K., Giersig M., Extraordinary optical transmission in nano-bridged plasmonic arrays mimicking a stable weakly-connected percolation threshold, OPTICS EXPRESS, ISSN: 1094-4087, DOI: 10.1364/OE.403034, Vol.28, No.21, pp.31425-31435, 2020

Abstract:
Ultrasensitive sensors of various physical properties can be based on percolation systems, e.g., insulating media filled with nearly touching conducting particles. Such a system at its percolation threshold featuring the critical particle concentration, changes drastically its response (electrical conduction, light transmission, etc.) when subjected to an external stimulus. Due to the critical nature of this threshold, a given state at the threshold is typically very unstable. However, stability can be restored without significantly sacrificing the structure sensitivity by forming weak connections between the conducting particles. In this work, we employed nano-bridged nanosphere lithography to produce such a weakly connected percolation system. It consists of two coupled quasi-Babinet complementary arrays, one with weakly connected, and the other with disconnected metallic islands. We demonstrate via experiment and simulation that the physics of this plasmonic system is non-trivial, and leads to the extraordinary optical transmission at narrowly defined peaks sensitive to system parameters, with surface plasmons mediating this process. Thus, our system is a potential candidate for percolation effect based sensor applications. Promising detection schemes could be based on these effects.

Affiliations:
Akinoglu E.M. - University of Melbourne (AU)
Luo L. - other affiliation
Dodge T. - other affiliation
Guo L. - South China Normal Universit (CN)
Akinoglu G.E. - other affiliation
Wang X. - other affiliation
Shui L. - South China Normal Universit (CN)
Zhou G. - South China Normal Universit (CN)
Naughton M.J. - other affiliation
Kempa K. - other affiliation
Giersig M. - IPPT PAN
3.  Feng K., Akinoglu E.M., Bozheyev F., Guo L., Jin M., Wang X., Zhou G., Naughton M.J., Giersig M., Magnetron sputtered copper bismuth oxide photocathodes for solar water reduction, JOURNAL OF PHYSICS D-APPLIED PHYSICS, ISSN: 0022-3727, DOI: 10.1088/1361-6463/abaf25, Vol.53, pp.495501-1-11, 2020

Abstract:
There is an urgent need for new materials that can catalyze or drive the photoelectrochemical (PEC) conversion of solar energy into chemical energy, i.e. solar fuels. Copper bismuth oxide (CBO) is a promising photocathode material for the photochemical reduction of water. Here, we systematically control the stoichiometry of CBO thin films prepared by reactive, direct-current magnetron co-sputtering from metallic Bi and Cu targets. The intrinsic photophysical and PEC material properties are investigated and evaluated in order to determine the optimum composition for hydrogen formation. Changing the stoichiometry of the films reveals a dramatic change in the optical band gap and crystal structure of CBO. The largest photocurrent density was achieved for a copper-to-bismuth ion ratio of 0.53, close to the CuBi2O4 stoichiometry, which yielded Jph = − 0.48 mA cm^−2 at 0 VRHE (RHE = reversible hydrogen electrode). This is the highest value to date for the photochemical reduction of water with CuBi2O4 without an externally applied bias. The absorbed photon-to-current efficiency and the photostability of the films in neutral and alkaline electrolytes were also investigated.

Keywords:
CuBi2O4, copper bismuth oxide, water reduction, water splitting, photocathode, magnetron sputtering

Affiliations:
Feng K. - other affiliation
Akinoglu E.M. - University of Melbourne (AU)
Bozheyev F. - other affiliation
Guo L. - South China Normal Universit (CN)
Jin M. - South China Normal Universit (CN)
Wang X. - other affiliation
Zhou G. - South China Normal Universit (CN)
Naughton M.J. - other affiliation
Giersig M. - IPPT PAN

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