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Streszczenie:
Solid polymer electrolytes with high ionic conductivity, dominant ion transport, and long-term electrochemical stability are essential for next-generation solid-state lithium batteries. In this study, a fully hybrid nanocomposite solid polymer electrolyte based on poly(ethylene oxide) (PEO), POSS-benzyl7(BF3Li)3 nano lithium salt, and POSSPEG13.3 nano plasticizer is developed using solution casting technique, in which both the salt and plasticizer possess organic–inorganic hybrid architectures. The optimized electrolyte containing 40 wt% POSSPEG13.3 exhibits a high room-temperature ionic conductivity of 8.64 × 10−4 S cm⁻¹ and follows Vogel–Tammann–Fulcher (VTF) behavior. Structural and thermal analyses reveal near-complete suppression of PEO crystallinity (∼1%) and good thermal stability up to ∼235 °C. The electrolyte shows excellent mechanical flexibility and a near-unity ion transference number (tion = 0.99). A wide electrochemical stability window of ∼4.7 V vs. Li/Li⁺ is obtained. Solid-state LiFePO4/Li cells deliver an initial discharge capacity of 169.3 mAh g⁻¹ at 0.1 C with 89.8% capacity retention after 100 cycles. These results demonstrate the effectiveness of the fully hybrid electrolyte design for solid-state lithium batteries.

Słowa kluczowe:
Solid polymer electrolyte, POSS lithium salt, Nano plasticizer, Ion transference number, Solid-state lithium batteries

Streszczenie:
This paper provides a comprehensive overview of the influence of 1-Butyl-1-Methylpyrrolidinium Trifluoromethanesulfonate (BMPyrrOTf)-ionic liquid on a new polymer electrolyte where Polyethylene oxide (PEO) as host and ammonium iodide (NH4I) as salt. These IL-doped solid polymer electrolyte were prepared using solution cast technique. Various characterisation techniques have been utilized to evaluate the qualitative and quantitative estimation of polymer electrolyte like Polarized microscopy (POM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Linear sweep voltammetry (LSV), Ionic transference no. (tion) and Impedance spectroscopy. Doping IL increases conductivity and highest achieve at 8 wt% of BMPyrrOTF with conductivity value reaches upto 4.15 × 10–5 S/cm at. Using Wagner’s polarization method, Ionic transference measurement support ionic conduction while stable potential window has further affirmed good electrochemical stability of films. The highest conducting IL-enriched polymer electrolyte sandwiched low-cost dye-sensitized solar cells (DSSCs) and electric double layer capacitors (EDLCs) have been developed, and their performance is conveniently appropriate.