Instytut Podstawowych Problemów Techniki
Polskiej Akademii Nauk

Partnerzy

Mattia Zangoli

CNR-ISOF (IT)

Ostatnie publikacje
1.  Zangoli M., Monti F., Zanelli A., Marinelli M., Flammini S., Spallacci N., Zakrzewska A., Lanzi M., Salatelli E., Pierini F., Di Maria F., Multifunctional Photoelectroactive Materials for Optoelectronic Applications Based on Thieno[3,4-b]pyrazines and Thieno[1,2,5]thiadiazoles, Chemistry - A European Journal, ISSN: 0947-6539, DOI: 10.1002/chem.202303590, pp.1-18, 2023

Streszczenie:
In this study, we introduce a novel family of symmetrical thiophene-based small molecules with a Donor–Acceptor–Donor structure. These compounds feature three different acceptor units: benzo[c][1,2,5]thiadiazole (Bz), thieno[3,4-b]pyrazine (Pz), and thieno[1,2,5]thiadiazole (Tz), coupled with electron donor units based on a carbazole-thiophene derivative. Using Density Functional Theory (DFT), we investigate how the molecular geometry and strength of the central acceptor unit impact the redox and spectroscopic properties. Notably, the incorporation of Pz and Tz moieties induces a significant redshift in the absorption and emission spectra, which extend into the near-infrared (NIR) region, simultaneously reducing their energy gaps (~1.4-1.6 eV). This shift is attributed to the increased coplanarity of the oligomeric inner core, both in the ground (S0) and excited (S1) states, due to the enhanced quinoidal character as supported by bond-length alternation (BLA) analysis. These structural changes promote better π-electron delocalization and facilitate photoinduced charge transfer processes in optoelectronic devices. Notably, we show that Pz- and Tz-containing molecules exhibit NIR electrochromic behavior and present ambivalent character in bulk heterojunction (BHJ) solar cells. Finally, theoretical calculations suggest that these molecules could serve as effective two-photon absorption (2PA) probes, further expanding their potential in optoelectronic applications.

Afiliacje autorów:
Zangoli M. - CNR-ISOF (IT)
Monti F. - CNR-ISOF (IT)
Zanelli A. - CNR-ISOF (IT)
Marinelli M. - inna afiliacja
Flammini S. - inna afiliacja
Spallacci N. - inna afiliacja
Zakrzewska A. - IPPT PAN
Lanzi M. - University of Bologna (IT)
Salatelli E. - University of Bologna (IT)
Pierini F. - IPPT PAN
Di Maria F. - CNR-ISOF (IT)
140p.
2.  Marinelli M., Candini A., Monti F., Boschi A., Zangoli M., Salatelli E., Pierini F., Lanzi M., Zanelli A., Gazzano M., Di Maria F., Push–pull thiophene-based small molecules with donor and acceptor units of varying strength for photovoltaic application: beyond P3HT and PCBM, Journal of Materials Chemistry C, ISSN: 2050-7526, DOI: 10.1039/d1tc02641k, Vol.9, No.34, pp.11216-11228, 2021

Streszczenie:
Here is reported an expedient synthesis implementing enabling technologies of a family of thiophene-based heptamers alternating electron donor (D) and acceptor (A) units in a D–A′–D–A–D–A′–D sequence. The nature of the peripheral A groups (benzothiadiazole vs. thienopyrrole-dione vs. thiophene-S,S-dioxide) and the strength of the donor units (alkyl vs. thioalkyl substituted thiophene ring) have been varied to finely tune the chemical-physical properties of the D–A oligomers, to affect the packing arrangement in the solid-state as well as to enhance the photovoltaic performances. The optoelectronic properties of all compounds have been studied by means of optical spectroscopy, electrochemistry, and density functional theory calculations. Electrochemical measurements and Kelvin probe force microscopy (KPFM) predicted a bifunctional behaviour for these oligomers, suggesting the possibility of using them as donor materials when blended with PCBM, and as acceptor materials when coupled with P3HT. Investigation of their photovoltaic properties confirmed this unusual characteristic, and it is shown that the performance can be tuned by the different substitution pattern. Furthermore, thanks to their ambivalent character, binary non-fullerene small-molecule organic solar cells with negligible values of HOMO and LUMO offsets were also fabricated, resulting in PCEs ranging between 2.54–3.96%.

Afiliacje autorów:
Marinelli M. - inna afiliacja
Candini A. - CNR-ISOF (IT)
Monti F. - CNR-ISOF (IT)
Boschi A. - CNR-ISOF (IT)
Zangoli M. - CNR-ISOF (IT)
Salatelli E. - University of Bologna (IT)
Pierini F. - IPPT PAN
Lanzi M. - University of Bologna (IT)
Zanelli A. - CNR-ISOF (IT)
Gazzano M. - CNR-ISOF (IT)
Di Maria F. - CNR-ISOF (IT)
140p.

Kategoria A Plus

IPPT PAN

logo ippt            ul. Pawińskiego 5B, 02-106 Warszawa
  +48 22 826 12 81 (centrala)
  +48 22 826 98 15
 

Znajdź nas

mapka
© Instytut Podstawowych Problemów Techniki Polskiej Akademii Nauk 2024