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Monika Michalska

Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)

Ostatnie publikacje
1.  Manippady S., Michalska M., Krajewski M., Bochenek K., Basista M.A., Zaszczyńska A., Czeppe T., Rogal , Jain A., One-step synthesis of a sustainable carbon material for high performance supercapacitor and dye adsorption applications, Materials Science and Engineering: B, ISSN: 0921-5107, DOI: 10.1016/j.mseb.2023.116766, Vol.297, No.116766, pp.1-14, 2023

Streszczenie:
The sustainable transformation of bio-waste into usable, material has gained great scientific interest. In this paper, we have presented preparation of an activated carbon material from a natural mushroom (Suillus boletus) and explor its properties for supercapacitor and dye adsorption applications. The produced cell exhibited a single electrode capacitance of ∼247 F g−1 with the energy and power density of ∼35 Wh kg−1 and 1.3 kW kg−1, respectively. The cell worked well for ∼20,000 cycles with ∼30% initial declination in capacitance. Three cells connected in series glowed a 2.0 V LED for ∼1.5 min. Moreover, ultrafast adsorption of methylene blue dye onto the prepared carbon as an adsorbent was recorded with ∼100% removal efficiency in an equilibrium time of three minutes. The performed tests indicate that the mushroom-derived activated carbon has the potential to become a high-performance electrode material for supercapacitors and an adsorbent for real-time wastewater treatment applications.

Słowa kluczowe:
Activated carbon, Amorphous material, Biomass, Polymer gel electrolyte, Supercapacitor, Dye adsorption

Afiliacje autorów:
Manippady S. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Krajewski M. - IPPT PAN
Bochenek K. - IPPT PAN
Basista M.A. - IPPT PAN
Zaszczyńska A. - IPPT PAN
Czeppe T. - Institute of Metallurgy and Materials Science, Polish Academy of Sciences (PL)
Rogal  - Institute of Metallurgy and Materials Science, Polish Academy of Sciences (PL)
Jain A. - IPPT PAN
100p.
2.  Jain A., Ziai Y., Bochenek K., Manippady Sai R., Pierini F., Michalska M., Utilization of compressible hydrogels as electrolyte materials for supercapacitor applications, RSC Advances, ISSN: 2046-2069, DOI: 10.1039/d3ra00893b, Vol.13, pp.11503-11512, 2023

Streszczenie:
Utilization of CoO@Co3O4-x-Ag (x denotes 1, 3, and 5 wt% of Ag) nanocomposites as supercapacitor electrodes is the main aim of this study. A new low-temperature wet chemical approach is proposed to modify the commercial cobalt oxide material with silver nanoparticle (NP) balls of size 1–5 nm. The structure and morphology of the as-prepared nanocomposites were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and N2 adsorption–desorption measurements. Hydrogels known to be soft but stable structures were used here as perfect carriers for conductive nanoparticles such as carbons. Furthermore, hydrogels with a large amount of water in their network can give more flexibility to the system. Fabrication of an electrochemical cell can be achieved by combining these materials with a layer-by-layer structure. The performance characteristics of the cells were examined by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and galvanostatic charge discharge (GCD). Cobalt oxide modified with 5 wt% Ag gave the best supercapacitor results, and the cell offers a specific capacitance of ∼38 mF cm−2 in two-electrode configurations.

Afiliacje autorów:
Jain A. - IPPT PAN
Ziai Y. - IPPT PAN
Bochenek K. - IPPT PAN
Manippady Sai R. - IPPT PAN
Pierini F. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
100p.
3.  Jain A., Manippady S., Tang R., Nishihara H., Sobczak K., Matejka V., Michalska M., Vanadium oxide nanorods as an electrode material for solid state supercapacitor, Scientific Reports, ISSN: 2045-2322, DOI: 10.1038/s41598-022-25707-z, Vol.12, No.21024, pp.1-12, 2022

Streszczenie:
The electrochemical properties of metal oxides are very attractive and fascinating in general, making them a potential candidate for supercapacitor application. Vanadium oxide is of particular interest because it possesses a variety of valence states and is also cost effective with low toxicity and a wide voltage window. In the present study, vanadium oxide nanorods were synthesized using a modified sol–gel technique at low temperature. Surface morphology and crystallinity studies were carried out by using scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy analysis. To the best of our knowledge, the as-prepared nanorods were tested with magnesium ion based polymer gel electrolyte for the first time. The prepared supercapacitor cell exhibits high capacitance values of the order of ~ 141.8 F g−1 with power density of ~ 2.3 kW kg−1 and energy density of ~ 19.1 Wh kg−1. The cells show excellent rate capability and good cycling stability.

Afiliacje autorów:
Jain A. - IPPT PAN
Manippady S. - IPPT PAN
Tang R. - inna afiliacja
Nishihara H. - inna afiliacja
Sobczak K. - inna afiliacja
Matejka V. - inna afiliacja
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
140p.
4.  Jain A., Michalska M., Zaszczyńska A., Denis P., Surface modification of activated carbon with silver nanoparticles for electrochemical double layer capacitors, Journal of Energy Storage, ISSN: 2352-152X, DOI: 10.1016/j.est.2022.105367, Vol.54, pp.105367-1-9, 2022

Streszczenie:
In the present work, we report the synthesis of surface modified activated carbon (AC). The surface of the activated carbon have been modified by using silver nanoparticles. The synthesis process is simple, cost effective and environment friendly. The modified-AC powders have been characterized by using X-ray diffraction, scanning electron microscopy and surface area and pore size measurements. The electrochemical performance of the prepared materials have been tested by fabricating symmetric configuration of EDLC by using magnesium-ion based polymer electrolytes. The cells have been tested by using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge-discharge technique. AC with 3 wt% of silver presents best results with specific capacitance of the order of 398 F g−1 energy density and power density of 55 Wh kg−1 and 2.4 kW kg−1 making it an interesting material for supercapacitor application.

Słowa kluczowe:
supercapacitor, activated carbon-silver composite, gel polymer electrolyte, electrochemical studies

Afiliacje autorów:
Jain A. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Zaszczyńska A. - IPPT PAN
Denis P. - IPPT PAN
100p.
5.  Michalska M., Buchberger D.A., Jasiński J.B., Thapa A.K., Jain A., Surface modification of nanocrystalline LiMn2O4 using graphene oxide flakes, Materials, ISSN: 1996-1944, DOI: 10.3390/ma14154134, Vol.14, No.15, pp.4134-1-13, 2021

Streszczenie:
In this work, a facile, wet chemical synthesis was utilized to achieve a series of lithium manganese oxide (LiMn2O4, (LMO) with 1–5%wt. graphene oxide (GO) composites. The average crystallite sizes estimated by the Rietveld method of LMO/GO nanocomposites were in the range of 18–27 nm. The electrochemical performance was studied using CR2013 coin-type cell batteries prepared from pristine LMO material and LMO modified with 5%wt. GO. Synthesized materials were tested as positive electrodes for Li-ion batteries in the voltage range between 3.0 and 4.3 V at room temperature. The specific discharge capacity after 100 cycles for LMO and LMO/5%wt. GO were 84 and 83 mAh g^−1, respectively. The LMO material modified with 5%wt. of graphene oxide flakes retained more than 91% of its initial specific capacity, as compared with the 86% of pristine LMO material.

Słowa kluczowe:
lithium manganese oxide, LiMn2O4, graphene oxide, cathode material, lithium ion battery

Afiliacje autorów:
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Buchberger D.A. - Uniwersytet Warszawski (PL)
Jasiński J.B. - inna afiliacja
Thapa A.K. - inna afiliacja
Jain A. - IPPT PAN
140p.
6.  Michalska M., Xu H., Shan Q., Zhang S., Gao Y., Jain A., Krajewski M., Dall'Agnese Y., Solution combustion synthesis of a nanometer-scale Co3O4 anode material for Li-ion batteries, Beilstein Journal of Nanotechnology, ISSN: 2190-4286, DOI: 10.3762/bjnano.12.34, Vol.12, pp.424-431, 2021

Streszczenie:
A novel solution combustion synthesis of nanoscale spinel-structured Co3O4 powder was proposed in this work. The obtained material was composed of loosely arranged nanoparticles whose average diameter was about 36 nm. The as-prepared cobalt oxide powder was also tested as the anode material for Li-ion batteries and revealed specific capacities of 1060 and 533 mAh·g^−1 after 100 cycles at charge–discharge current densities of 100 and 500 mA·g^−1, respectively. Moreover, electrochemical measurements indicate that even though the synthesized nanomaterial possesses a low active surface area, it exhibits a relatively high specific capacity measured at 100 mA·g^−1 after 100 cycles and a quite good rate capability at current densities between 50 and 5000 mA·g^−1.

Słowa kluczowe:
anode material, cobalt oxide, lithium-ion battery, solution combustion synthesis, transition metal oxide

Afiliacje autorów:
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Xu H. - inna afiliacja
Shan Q. - inna afiliacja
Zhang S. - inna afiliacja
Gao Y. - inna afiliacja
Jain A. - IPPT PAN
Krajewski M. - IPPT PAN
Dall'Agnese Y. - inna afiliacja
100p.
7.  Jain A., Ghosh M., Krajewski M., Kurungot S., Michalska M., Biomass-derived activated carbon material from native European deciduous trees as an inexpensive and sustainable energy material for supercapacitor application, Journal of Energy Storage, ISSN: 2352-152X, DOI: 10.1016/j.est.2020.102178, Vol.34, pp.102178-1-9, 2021

Streszczenie:
Activated carbons are one of the possible electrode materials for supercapacitors (SCs), which are widely used in commercial applications. Herein, we reported the synthesis of a novel activated carbon derived through a cavitation process from the mixture of native European deciduous trees, Birch, Fagaceae, and Carpinus betulus (commonly known as European hornbeam), which was employed as the electrode material in SC. From the morphological and structural characterization, we observed that the prepared sample is a desirable carbon with good porosity and high specific surface area of about 614 m^2 g^-1. The electrochemical properties of the synthesized material were evaluated with a three-electrode configuration in 1.0 M H2SO4 electrolyte. It was found that in device mode, the carbon material delivers a specific capacitance of 24 F g^-1 at 0.25 A g^-1 with excellent cycling stability of over 10000 consecutive charge/discharge cycles. Thus, our studies demonstrate the facile synthesis of biomass-derived carbon and its application as a versatile electrode material for SC applications.

Słowa kluczowe:
biomass, carbon material, deciduous trees, electrode material, supercapacitor

Afiliacje autorów:
Jain A. - IPPT PAN
Ghosh M. - inna afiliacja
Krajewski M. - IPPT PAN
Kurungot S. - inna afiliacja
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
100p.
8.  Lee B.Y., Chu C.T., Krajewski M., Michalska M., Lin J.Y., Temperature-controlled synthesis of spinel lithium nickel manganese oxide cathode materials for lithium-ion batteries, CERAMICS INTERNATIONAL, ISSN: 0272-8842, DOI: 10.1016/j.ceramint.2020.05.124, Vol.46, No.13, pp.20856-20864, 2020

Streszczenie:
In this work, we successfully synthesized series of LiNi0.5Mn1.5O4 (LNMO) cathode materials with spinel structure by using a facile sol-gel method and then calcined at various temperature ranging from 600 to 1000 °C. The application of different calcination temperatures significantly influenced the surface morphology, stoichiometry and crystalline nature of the as-synthesized LNMO material. According to the results of physical characterizations, the LNMO materials calcined at various temperatures mainly revealed the stoichiometric disordered Fd-3m structure with a small amount of well-ordered P4332 phase. The structural analysis also exhibited that the control of the calcination temperature contributed to the higher crystalline nature. Moreover, the morphological investigations indicated that the increasing calcination temperatures caused the formation of large micron-sized LNMO material. In turn, the electrochemical evaluations revealed the impact of the calcination temperatures on enhancing the electrochemical performances of the LNMO electrode materials up to 900 °C. The LNMO electrode calcined at 900 °C exhibited an impressive initial discharge specific capacity of ca. 142 mAh g^−1 between 3.5 and 4.9 V vs. Li/Li+, and remarkably improved capacity retention of 97% over 50 cycles. Those excellent electrochemical properties were associated with the presence of the dominant Fd-3m phase over the P4332 phase. Additionally, the results of the corrosion and dissolution tests which were performed for all calcined LNMO materials in order to estimate the amount of manganese and nickel ions leached from them, proved that the micro-sized LNMO calcined at 900 °C was the most stable.

Słowa kluczowe:
spinel LiNi0.5Mn1.5O4, sol-gel synthesis, calcination temperature, cathode material, lithium-ion batteries

Afiliacje autorów:
Lee B.Y. - Tatung University (TW)
Chu C.T. - inna afiliacja
Krajewski M. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Lin J.Y. - National Chung Cheng University (TW)
100p.
9.  Krajewski M., Liao P.Y., Michalska M., Tokarczyk M., Lin J.Y., Hybrid electrode composed of multiwall carbon nanotubes decorated with magnetite nanoparticles for aqueous supercapacitors, Journal of Energy Storage, ISSN: 2352-152X, DOI: 10.1016/j.est.2019.101020, Vol.26, pp.101020-1-7, 2019

Streszczenie:
This work describes a use of a composite nanomaterial which consists of multiwall carbon nanotubes covered by iron oxide nanoparticles as a hybrid electrode in aqueous supercapacitor. The investigated nanomaterial was manufactured in a two-step simple chemical synthesis in which the first step was a functionalization of carbon nanotubes whereas the second one was the deposition of iron oxide. According the morphological and structural characterization, the carbon nanotubes with diameters of 10–40 nm were successfully covered by randomly-dispersed magnetite nanoparticles with average diameter of 10 nm. Moreover, the thermogravimetric analysis results indicated that the mass ratio between carbon nanotubes and iron oxide nanoparticles was about 65–35%. The electrochemical performance of studied hybrid electrode was tested in 1M aqueous KCl electrolyte. The highest specific capacitance of 143 F g^‒1 was recorded at a discharge current density of 1 A g^‒1. The investigated nanomaterial also exhibited excellent cycling stability i.e. 81% retention of the initial capacitance after 3000 cycles.

Słowa kluczowe:
hybrid electrode, magnetite, multiwall carbon nanotube, nanocomposite, supercapacitor

Afiliacje autorów:
Krajewski M. - IPPT PAN
Liao P.Y. - Tatung University (TW)
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Tokarczyk M. - Uniwersytet Warszawski (PL)
Lin J.Y. - Tunghai University (CN)
100p.

Abstrakty konferencyjne
1.  Jain A., Michalska M., Pietrzyk-Thel P., Development of surface modified carbon material electrode for EDLC application, E-MRS 2023, The Fall Meeting of the European Materials Research Society, 2023-09-18/09-21, Warszawa (PL), pp.1-1, 2023

Słowa kluczowe:
Supercapacitors, Activated Carbon, Polymer gel electrolyte, Surface modification

Afiliacje autorów:
Jain A. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Pietrzyk-Thel P. - IPPT PAN
2.  Jain A., Michalska M., Manippady S.R., Fabrication of electrochemical double layer capacitor using surface modified WCNTs as an electrode materials, THERMEC 2023, International Conference on PROCESSING & MANUFACTURING OF ADVANCED MATERIALS Processing, Fabrication, Properties, Applications, 2023-07-02/07-07, Wiedeń (AT), pp.1-1, 2023

Słowa kluczowe:
Supercapacitors, MWCNTs, Polymer gel electrolyte, Surface modification

Afiliacje autorów:
Jain A. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
Manippady S.R. - IPPT PAN
3.  Jain A., Michalska M., Modified carbon materials for energy storage application, 2nd annual meeting of the AtomDeC project, 2022-11-02/11-04, Smolenice (SK), pp.1-2, 2022

Słowa kluczowe:
Supercapacitors, Activated carbon, Polymer gel electrolyte

Afiliacje autorów:
Jain A. - IPPT PAN
Michalska M. - Łukasiewicz Research Network‒Institute of Electronic Materials Technology (PL)
4.  Jain A., Michalska M., Silver-modified carbon material and its application in supercapacitor devices, FuNaM-3, 3rd International Workshop on Functional Nanostructured Materials, 2021-10-06/10-08, Kraków (PL), pp.1-1, 2021

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